Just out @Inorganic Chemistry! Excellent cooperation with Prof. Pilar Garcia Armada from Universidad Politécnica de Madrid during a few weeks of Ola Mrzygłód internship in Madrid. The paper describes the synthesis of DDSQ-based silylferrocene intriguing G1 and G2 dendrimers. Our investigation also encompassed the examination of their properties, including electrochemical behaviour. This study marks the 1st example of modifying double-decker silsesquioxane cores with ferrocene groups while simultaneously representing one of the scarce instances of dendrimers exhibiting an open double-decker silsesquioxane core.
Just look for yourself:
A. Mrzygłód, M. Rzonsowska, M. P. García-Armada, B. Dudziec, M. Nowicki
Metallodendrimers Unveiled: Investigating the Formation and Unique Features of Double-Decker Silsesquioxane-Based Silylferrocene Dendrimers
Inorg. Chem. 2023, (accepted), DOI: 10.1021/acs.inorgchem.3c02628